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Mail: University of Houston
Cullen College of Engineering
E421 Engineering Bldg 2, 4722 Calhoun Rd, Houston, TX 77204-4007
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CULLEN COLLEGE OF ENGINEERING

University of Houston Cullen College of Engineering

Department Event / Seminar

[CHBE] Deciphering Surface Mediated Thermo- and Electro- Catalytic Reactions with in-situ Spectroscopies

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Date: 

Friday, October 27, 2017 - 10:30am

Location: 

Room L2D2

Developing active, selective and energy efficient heterogeneous catalytic processes is key to a sustainable future because heterogeneous thermo-/electro- catalysis is at the center of the chemicals and energy industries. Molecular level understanding of the interaction between the substrate and the surface provides the basis for rational catalyst design. Application and development of spectroscopic techniques capable of probing properties of catalytic sites and identifying reaction intermediates at or close to reaction conditions are key to establishing reliable structure-activity relations. We employ attenuated total reflection – surface enhanced infrared absorption spectroscopy (ATR-SEIRAS) to investigate the electrode surface mediated reactions, e.g., electrochemical reduction of CO2, and interplay between electrolytes and electrodes, e.g., the influence of nonspecific adsorption of cations on the adsorbates. Combining with isotopic labeling and electrokinetic techniques, a comprehensive mechanistic understanding of surface-mediated electrochemical processes could be achieved. Further, variations of infrared spectroscopic techniques are also powerful in obtaining mechanistic information biomass upgrading processes in both gas and liquid phases, which will be demonstrated with several representative examples.

 

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